期刊
MENDELEEV COMMUNICATIONS
卷 30, 期 3, 页码 344-346出版社
ELSEVIER
DOI: 10.1016/j.mencom.2020.05.028
关键词
selective recognition; conformation; stereoelectronic effects; closed-shell interactions
资金
- Russian Science Foundation [19-73-20090]
- Russian Foundation for Basic Research [20-03-00867]
- Russian Science Foundation [19-73-20090] Funding Source: Russian Science Foundation
Two new bis-azoles derived from 1,5-dimethylbispidin-9-one were synthesized and structurally characterized. In both cases the bispidine backbone adopts the double chair conformation, which is also confirmed by calculations. In both structures, the azole rings are spatially pre-reorganized for the supramolecular interactions with the proper substrates like electron-rich aromatic compounds; the origin and nature of tiny intramolecular interactions are discussed in view of conformation stability.
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