期刊
MATERIALS AND CORROSION-WERKSTOFFE UND KORROSION
卷 71, 期 11, 页码 1885-1902出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/maco.202011709
关键词
acid inhibitors; chemisorption; corrosion inhibitor; hydrochloric acid; mild steel
资金
- Federal University of Rio Grande do Sul
- Federal Institute of Mato Grosso do Sul
- CAPES
- CNPq [155274/2018-0, 306640/2016-3, 307723/2018-6]
- CAPES PNPD [88887.463867/2019-00]
- Federal University of Bahia
- CNPq
The aim of the present study is to evaluate the performance of N-methyl-2-hydroxyethylammonium oleate ([m-2HEA][Ol]) as a corrosion inhibitor for mild steel in a 0.1-mol/L hydrochloric acid solution and also investigate the role of chloride in the inhibition mechanism. This protic ionic liquid (PIL) has formerly shown a high efficiency as a corrosion inhibitor in a neutral chloride medium. Electrochemical and weight loss measurements, surface contact angle determination, scanning electron microscopy, and Raman spectroscopy were used to understand the factors that influence the response of the studied inhibitor. Results revealed that [m-2HEA][Ol] behaves as a mixed-type adsorption inhibitor, by blocking cathodic sites and by modifying the activation energy of the anodic reaction, and it can reach up to 94-97% of inhibition efficiency. PIL adsorption was enhanced by the excess of positive charge of the mild steel. The effect of inhibitor molecule has been discussed to propose a mechanism that explains the inhibitory action of the corrosion inhibitor, pointing out the role of chloride in the inhibition mechanism.
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