期刊
MASS SPECTROMETRY REVIEWS
卷 40, 期 4, 页码 359-380出版社
WILEY
DOI: 10.1002/mas.21643
关键词
mass spectrometry; direct determination; solid samples; element analysis; isotopic analysis; nonmetals; electronegative elements
类别
资金
- Russian Science Foundation [17-73-20089]
- Russian Science Foundation [17-73-20089] Funding Source: Russian Science Foundation
This paper mainly discusses the application of mass spectrometric techniques for the quantification of N, O, F, Cl, and Br in solid samples, pointing out the issues with conventional techniques and emphasizing the flexibility and robustness of mass spectrometry techniques.
The determination of nonmetals, first of all, the most electronegative ones-nitrogen, oxygen, fluorine, chlorine, and bromine, poses the highest challenge for element analysis. These elements are characterized by high reactivity, volatility, high ionization energy, and the absence of intensive spectral lines in the optical spectral range. Conventional techniques of their quantification include considerable wet chemistry stages so the application of these techniques for the solid sample is highly laborious and prone to uncontrollable uncertainties. Additionally, current development in material science and other areas requires the quantification of the elements at lower levels with good sensitivity. Owing to their robustness and flexibility, mass spectrometry techniques provide vast possibilities for the quantification, spatial and isotopic analysis, including the solutions for direct analysis of solids. The current review focuses on the application of major mass spectrometric techniques for the quantification of N, O, F, Cl, and Br in solid samples. The following techniques are mainly considered: thermal ionization mass spectrometry (TIMS), isotope-ratio MS (IRMS), secondary ion MS (SIMS), inductively coupled plasma MS (ICP-MS), and glow discharge MS (GDMS); as the most accessible and widely applied for the purpose. General ionization issues, advantages, limitations, and novel methodological solutions are discussed.
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