期刊
MACROMOLECULES
卷 53, 期 15, 页码 6672-6681出版社
AMER CHEMICAL SOC
DOI: 10.1021/acs.macromol.0c00857
关键词
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资金
- NSF as part of the Center for High Resolution Neutron Spectroscopy
- NIST-NRC Postdoctoral Research Fellowship Program
This article explores the relationship between the nano- to picosecond dynamics, as quantified by elastic incoherent neutron scattering, in polycarbonate (PC) glasses with their mechanical toughness. We establish a robust correlation between mechanical toughness and these fast relaxations, suggesting that they are a critical pathway for dissipating energy under impact conditions. This understanding is developed across a series of PCs, where the impact strength is either systematically increased through the incorporation of 1,4-cyclohexyl linkages into the PC backbone or diminished through the addition of antiplasticizer molecules that embrittle the glass. Across this homologous series, a connection emerges between the level of anharmonicity in mean-square-atomic displacements of different PCs and their impact strength. We interpret the level anharmonicity in these fast dynamics as a metric of the collective, many-atom relaxations, suggesting that collective relaxation processes on the timescale of nano- to picosecond are critical for toughness in polymer glasses.
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