期刊
LANGMUIR
卷 36, 期 27, 页码 7844-7849出版社
AMER CHEMICAL SOC
DOI: 10.1021/acs.langmuir.0c00812
关键词
-
资金
- Elements Strategy Initiative for Catalysts & Batteries (ESICB)
- Ministry of Education, Culture, Sports, Science, and Technology (MEXT) of Japan [JPMSPO9A19UT0048]
- Japan Society for the Promotion of Science (JSPS) [17H01182]
- Grants-in-Aid for Scientific Research [17H01182] Funding Source: KAKEN
In this report, we introduced poly(n-vinylpyridine) (PnVP, n = 2, 4) as an electron-donating stabilizer for small (<2 nm) Au clusters and elucidated how coordinating pyridines affect the physical, optical, chemical, and catalytic properties of Au clusters. Spectroscopic measurements and theoretical calculation suggested the high electron-donating ability of PnVP. PnVP-stabilized Au dusters improved robustness in aerobic oxidation of alcohols compared to poly(N-vinyl-2-pyrrolidone)-stabilized ones, while retaining catalytic activities.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据