4.7 Article

A novel high entropy CoFeCrNiCu alloy filler to braze SiC ceramics

期刊

JOURNAL OF THE EUROPEAN CERAMIC SOCIETY
卷 40, 期 9, 页码 3391-3398

出版社

ELSEVIER SCI LTD
DOI: 10.1016/j.jeurceramsoc.2020.03.044

关键词

SiC ceramic; High entropy alloy; Brazing; Microstructure; Shear strength

资金

  1. National Natural Science Foundation of China [51704001, 51772028]
  2. Talent Project of Anhui Province [Z175050020001]
  3. Natural Science Foundation of Anhui Province [KJ2018A0860]
  4. Talent Project of Anhui Polytechnic University
  5. Anhui Provincial Grant for high-level platform construction
  6. Academy of Finland [311934]
  7. Opening Project of State Key Laboratory of High Performance Ceramics and Superfine Microstructure [SKL201902SIC]

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In order to reduce intermetallic compound formations in brazed joints, a CoFeCrNiCu high entropy alloy was invented and employed to braze SiC ceramics. Results show that SiC ceramics were tightly and strongly brazed with the CoFeCrNiCu filler. Microstructure, phase and shear strength were systematically studied for joints brazed at different temperature. Main compositions were identified as high-entropy FCC, Cu(s, s), Si(s, s), and Cr23C6 phases, regardless the brazing temperature differences. After being brazed at 1453 K, the joint reached a maximum shear strength of 60 MPa, much higher than those brazed with conventional AgCuTi filler. Thanks to high entropy effect of CoFeCrNiCu filler, random solid solution turned out in the seam and benefitted joint quality. The successful use of CoFeCrNiCu high entropy alloy as fillers can expand the application range of high entropy alloys and provide a new filler system to braze ceramics.

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