期刊
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
卷 142, 期 31, 页码 13459-13468出版社
AMER CHEMICAL SOC
DOI: 10.1021/jacs.0c04863
关键词
-
资金
- National Natural Science Foundation of China [21901104]
- Thousand Talents Program for Young Scholars
- Southern University of Science and Technology
- Shenzhen Nobel Prize Scientists Laboratory Project [C17783101]
- Guangdong Provincial Key Laboratory of Catalysis [2020B121201002]
- China Postdoctoral Science Foundation [2019M651153]
- Shenzhen Clean Energy Research Institute [CERI-KY-2019-003]
A rhodium-catalyzed tandem enantioselective C-H silylation/alkene hydrosilylation of dihydrosilanes, which enables the streamlined construction of a wide range of silicon-stereogenic silanes, is successfully developed. This process involves a SiH2-steered highly enantioselective C-H silylation to furnish the corresponding desymmetric monohydrosilanes, which are subsequently trapped with alkenes in a stereospecific fashion to build functionally diverse asymmetrically tetrasubstituted silanes. This general strategy combines readily available dihydrosilanes and alkenes to construct various enantioenriched silicon-stereogenic silanes, including 9-silafluorenes, Si-bridged ladder compounds, and benzosilolometallocenes, in a single step with good to excellent yields and enantioselectivities.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据