FeO6 Octahedral Distortion Activates Lattice Oxygen in Perovskite Ferrite for Methane Partial Oxidation Coupled with CO2 Splitting

Modulating lattice oxygen in metal oxides that conducts partial oxidation of methane in balancing C-H activation and syngas selectivity remains challenging. This paper describes the discovery of distorting FeO6 octahedra in La1-xCexFeO3 (x = 0, 0.25 0.5, 0.75, 1) orthorhombic perovskites for the promotion of lattice oxygen activation. By combined electrical conductivity relaxation measurements and density functional theory calculations studies, this paper describes the enhancement of FeO6 octahedral distortion in La1-xCexFeO3 promoting their bulk oxygen mobility and surface oxygen exchange capability. Consequently, LaosCeasFeO(3) with the highest FeO6 distortion achieves exceptional syngas productivity of similar to 3 and 8 times higher than LaFeO(3)( )and CeFeO3, respectively, in CH4 partial oxidation step with simultaneous high CO2 conversion (92%) in the CO2-splitting step at 850 degrees C. The results exemplify the feasibility to tailor the active lattice oxygen of perovskite by modulating the distortion of BO6 in ABO(3), which ultimately influences their reaction performance in chemical looping processes.