期刊
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
卷 142, 期 28, 页码 11988-11992出版社
AMER CHEMICAL SOC
DOI: 10.1021/jacs.0c04159
关键词
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资金
- University of Delaware (UD)
- University of San Diego (USD)
- Camille and Henry Dreyfus Foundation
- National Science Foundation [CHE-1800011, CHE1764307]
- NSF [CHE-0421224, CHE-1048367, CHE-0840401]
- NIH [P20GM104316, P30GM110758, S10RR02692, S10OD016267]
Phosphonate-directed ortho C-H borylation of aromatic phosphonates is reported. Using simple starting materials and commercially accessible catalysts, this method provides steady access to o-phosphonate arylboronic esters bearing pendant functionality and flexible substitution patterns. These products serve as flexible precursors for a variety of highly substituted phosphoarenes, and in situ downstream functionalization of the products is described.
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