期刊
JOURNAL OF POWER SOURCES
卷 468, 期 -, 页码 -出版社
ELSEVIER
DOI: 10.1016/j.jpowsour.2020.228363
关键词
Nanosheet stack; Interfacial charge storage; Capacitive contribution; High power output; Sandwich-like structure
资金
- Xiamen Municipal Bureau of Science and Technology [3502Z20182023]
- National Natural Science Foundation of China [21905282]
Poor rate capability and cyclability are the major barriers to using TiO2 as the next generation anode material for high-performance lithium-ion batteries. In this study, a sandwich-like composite consisting of atomically defined two-dimensional (2D) carbon nanosheet is constructed by the confined synthesis in the galleries of layered TiO2 nanosheet with the superior cycling and rate performances as the anode material for lithium-ion batteries. It is first experimentally revealed that the interfacial charge storage between unilamellar TiO2 nanosheet and carbon nanosheet in the Carbon/TiO2 nanosheet stack and the excellent structure stability during the discharge/charge process contribute to the superior performance of the composites. The resultant composite exhibits a high specific capacity (568 mAh g(-1)) with a specific energy of 407.4 Wh kg(-1) at a specific power of 71.7 W kg(-1), and remains 88.0 Wh kg(-1) at a specific power of 9.0 kW kg(-1). Apart from promising lithium-ion battery anode, this 2D Carbon/TiO2 composite also has immense potential for applications in other areas such as sodium/potassium-ion batteries, supercapacitor, and catalysis.
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