期刊
JOURNAL OF PHOTOCHEMISTRY AND PHOTOBIOLOGY A-CHEMISTRY
卷 403, 期 -, 页码 -出版社
ELSEVIER SCIENCE SA
DOI: 10.1016/j.jphotochem.2020.112839
关键词
Divalent europium ion; 5d-luminescence; Coordination environment; Anion; Electronically excited states; Polarizability
资金
- Russian Foundation for Basic Research [18-33-00201]
- Ministry of Education and Science of the Russian Federation [2019-05-595-000-058]
The photoluminescence spectra of crystalline europium dihalides EuL2 (L = Cl, Br, and I) and solutions of complexes of divalent europium EuL2(THF)(2) (L = Cl, NO3, fod, tmhd, acac, Ac) in tetrahydrofuran were registered. The bathochmmic shift of the Eu2+ 5d-4f luminescence maxima is typical for all studied compounds. Its value decreases in the series Cl- > Br- > NO3- > Ac- > acac- > fod- > tmhd- and correlates well with the mean polarizabilities of the anionic ligands.
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