期刊
JOURNAL OF ORGANOMETALLIC CHEMISTRY
卷 920, 期 -, 页码 -出版社
ELSEVIER SCIENCE SA
DOI: 10.1016/j.jorganchem.2020.121336
关键词
Ferrocene; Burning rate catalysts; Anti-migration behavior
资金
- National Natural Science Foundation of China [51673170, 5181153009, 21611530689, 21472168]
For overcoming the migration problems of ferrocene (Fc)-based burning rate catalysts (BRCs) as well as for enhancing burning rate (BR) of ammonium perchlorate (AP)-based propellants, ferrocenylated-amino pyridines (AP-Fcs) and ferrocenylated-amino thiazoles (AT-Fcs) have been synthesized. The synthesis of AP-Fcs and AT-Fcs was confirmed by nuclear magnetic resonance (H-1 NMR). Electrochemical properties of these ferrocenylated derivatives were explored by cyclic voltammetry (CV). The BR catalytic activities of AP-Fcs and AT-Fcs on thermal decomposition of AP were examined by thermogravimetric (TG) and differential thermogravimetric (DTG) techniques. Thermal analysis results showed that AP-Fcs and AT-Fcs showed good BR catalytic effects on thermal decomposition of AP. AP-Fcs and AT-Fcs were also applied for anti-migration studies in comparison with catocene (Cat) and ferrocene. It was found that AP-Fcs and AT-Fcs displayed anti-migratory behavior. (C) 2020 Elsevier B.V. All rights reserved.
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