期刊
JOURNAL OF ORGANIC CHEMISTRY
卷 85, 期 15, 页码 9614-9621出版社
AMER CHEMICAL SOC
DOI: 10.1021/acs.joc.0c00936
关键词
-
资金
- Natural Science Foundation of China [21801096, 21772067]
- Natural Science Foundation of Zhejiang Province [LQ18B020005, LY19B020004]
- University Student Research Innovation Team of Zhejiang Province [2019R417020]
- University Student Research Innovation Team of Jiaxing University [CD8517193146]
A facile synthesis of benzo[3,4]indolo[1,2-b]-isoquinolin-8-ones is described. Under copper catalysis, the reaction proceeds with a high efficiency and a broad reaction scope. A deuteration experiment shows that the KM value is 2.85. From the results on mechanism studies, copper-catalyzed C-H activation, intramolecular cis-addition of alkynes, and reductive elimination are involved. Moreover, this skeleton is indeed a new fluorophore, and its photophysical properties are also investigated.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据