期刊
JOURNAL OF ORGANIC CHEMISTRY
卷 85, 期 15, 页码 9850-9862出版社
AMER CHEMICAL SOC
DOI: 10.1021/acs.joc.0c01162
关键词
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资金
- NSF of China [21901262, 21772043]
- China Postdoctoral Science Foundation [2019M650229]
- Guangdong Provincial Key Laboratory of Chiral Molecule and Drug Discovery [2019B030301005]
- National Mega-project for Innovative Drugs [2019ZX09721001-006-001]
- Program for Guangdong Introducing Innovative and Entrepreneurial Teams [2016ZT06Y337]
A Rh(II)/Ag(I)-cocatalyzed three component reaction of propargylic alcohol-Co-2(CO)(6) complexes with diazo compounds and benzyl alcohols is described, which represents the first trapping process of oxonium ylides with carbocations via the S(N)1/S(N)1'-type pathway. This transformation provides an efficient approach for construction of dicobalt hexacarbonyl-complexed 3,3-disubstituted oxindoles. Further derivatization of the product, initiated by the deprivation of the dicobalt species, gives the 3,3-disubstituted oxindoles with the ene alkynyl group and the privileged spirooxindole-vinyldihydropyran structure.
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