期刊
JOURNAL OF ORGANIC CHEMISTRY
卷 85, 期 17, 页码 11072-11079出版社
AMER CHEMICAL SOC
DOI: 10.1021/acs.joc.0c01579
关键词
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资金
- Spanish Ministerio de Economia, Industria y Competitividad [CTQ2015-66624-P, CTQ2017-88171-P]
- Spanish Ministerio de Ciencia, Innovacion y Universidades [PGC2018-096616-B-I00]
- University of Alicante [VIGROB-316/19, UADIF19-106]
The straightforward synthesis of N,N-disubstituted formamides using a combination of 1,1,1,3,3,3-hexafluoroispropanol (HFIP) and H2O2 is described. The unique features of HFIP allowed the utilization of a green oxidant such as H2O2, and the products, arising from an oxidation-rearrangement sequence, were obtained in good to high yields under smooth reaction conditions.
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