Structural, optical, dielectric, and multiferroic properties of sodium and nickel co-substituted barium titanate ceramics

Narrowing the bandgap energy of perovskite ferroelectrics is a potential task for improving PV applications. This study examined the effect of Ni2+/Na(+)co-substitution on the structural, optical, electrical, and magnetic properties of Ba1-x(Ni-x/2,Na-x)TiO3(BTNaNi-x) ceramics, where (0 <= x <= 0.08), prepared by solid-state reaction method. X-ray diffraction along with structure refinement verifies the existence of perovskite structure with a tetragonal phase in all samples. The morphological study reveals a non-uniform grain size distribution with a decrease in grain size with an increase in co-substitution concentration. XPS study gives direct evidence of oxygen vacancies in the investigated sample. The oxygen vacancies and octahedral distortion accompanying the Ni2+/Na(+)co-substitution significantly reduce the optical bandgap of BaTiO(3)ceramics from 3.14 to 2.688 eV. The temperature dependence of the dielectric constant is measured in the range of 30-250 degrees C at the frequency of 1 kHz. The results reveal that the transition temperature gradually decreased with an increase in Ni(2+)and Na(+)concentrations. This phenomenon was interpreted based on reducing grain size and tetragonality with co-substitution. The ferroelectric and magnetic properties are determined by (P-E) and (M-H) hysteresis loops at room temperature.Magnetic properties are significantly enhanced with an increase in the Ni2+, Na(+)contents in the system. The correlation between the ESR width parameter (Delta H) and asymmetry parameter (Pays) with concentrations (x) reveals that the sample withx = 0.08 has a strong magnetic nature compared to other samples.

Automated summary

This study explores the effects of Ni2+/Na(+)co-substitution on the properties of Ba1-x(Ni-x/2,Na-x)TiO3(BTNaNi-x) ceramics, revealing a significant reduction in optical bandgap with the presence of oxygen vacancies and octahedral distortion. The increase in Ni2+ and Na(+)content leads to enhanced magnetic properties, with the sample at x = 0.08 exhibiting the strongest magnetic nature compared to others.