期刊
JOURNAL OF MATERIALS SCIENCE & TECHNOLOGY
卷 67, 期 -, 页码 226-236出版社
JOURNAL MATER SCI TECHNOL
DOI: 10.1016/j.jmst.2020.06.023
关键词
Functionalized carbon dots; Corrosion; Graphene; Self-healing
资金
- Scientific Research Foundation of Jiangxi University of Science and Technology [205200100421]
- Jiangxi Provincial Department of Education [GJJ190469]
- Postdoctoral fund of Jiangxi Province [2019KY29]
- Research and Development Project of Ganzhou
- Science and Technology Innovation Talents Program of Ganzhou
- Program of Qingjiang Excellent Young Talents (Jiangxi University of Science and Technology)
Functionalized carbon dots were used to modify graphene and prepare CDs modified graphene/epoxy coatings with excellent self-healing and corrosion resistance properties. The highly dispersed graphene in the coating acted as a physical barrier to protect the steel, contributing to its superior protective performance.
Functionalized carbon dots (CDs) obtained from citric acid derivative were selected as intercalator to modify graphene and then dispersed into epoxy matrix to prepare CDs modified graphene/epoxy (CDs-G/EP) coatings. Meanwhile, their microstructure, self-healing and corrosion resistance behaviors were analyzed deeply. Structural characterizations indicated the formation of pi-pi interaction between functionalized carbon dots and graphene. By observation, the dispersion and interface compatibility of graphene were greatly enhanced by CDs. The change rules of electrochemistry results implied that the addition of 0.5 wt.% CDs-G in EP coating (CDs-G0.5 %/EP) demonstrated a superior protective property on steel, which was attributed to the physical barrier of highly dispersed graphene and the self-healing ability of CDs. After 50 days immersion, the oxygen permeability coefficient and water absorption of CDs-G0.5 %/EP coating were only 4.27 x 10(-13) cm(3) cm cm(-2) s(-1) Pa-1 and 4.4 %, respectively. (C) 2021 Published by Elsevier Ltd on behalf of The editorial office of Journal of Materials Science & Technology.
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