期刊
JOURNAL OF INORGANIC AND ORGANOMETALLIC POLYMERS AND MATERIALS
卷 30, 期 11, 页码 4342-4349出版社
SPRINGER
DOI: 10.1007/s10904-020-01659-7
关键词
Silicone-acrylic emulsion; Flame retardant; Phosphate; Thermal properties
资金
- National Key R&D Program of China [2017YFB0309400, 2017YFB0309100]
- National Natural Science Foundation of China [51303022]
- Fundamental Research Funds for the Central Universities [2232015D3-17]
- PhD Foundation for Innovation of Donghua University [17D310513]
- China Scholarship Council (CSC) [201706630095]
The acrylic adhesives with the flame-retardant property are necessary to meet the safety requirement in electrostatic flocking. In this study, acrylic emulsion chemically modified with phosphorus and silicone, PSE, with core-shell structure, was synthesized by introducing the vinyl silicone oil and phosphor-containing monomer (PAM-100) onto the molecular chain of acrylic ester polymer in the core and shell layer, respectively. Subsequently, the silicone-acrylic adhesive with flame retardation (FR-SA) was prepared by mixing PSE with inorganic flame-retardant, Al(OH)(3). The acrylic adhesive obtains the excellent flame retardation under a low addition of Al(OH)(3)when the ratio of PAM-100 is 5%, while the commercial adhesive needs a high addition of the inorganic flame retardant to realize the satisfactory performance. FR-SA in this work has a great potential application as intrinsically flame-retardant electrostatic flocking adhesive.
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