期刊
JOURNAL OF HAZARDOUS MATERIALS
卷 395, 期 -, 页码 -出版社
ELSEVIER
DOI: 10.1016/j.jhazmat.2020.122692
关键词
ZIF-67; Electrospinning; Polyacrylonitrile; Amidoxime functionalization; Uranium extraction
资金
- National Natural Science Foundation of China [NSFC-21671170, 21673203, 21201010]
- Top-notch Academic Programs Project of Jiangsu Higher Education Institutions (TAPP)
- Natural Science Foundation of Jiangsu Province [BK20170999]
- Yangzhou University
Capturing uranium (U(VI)) ions from wastewater and seawater is highly attractive for the environment and clean energy with the increasing deficiency of land sources. Howbeit, the massive volume of water and the ultralow concentration of U(VI) pose a substantial challenge to the industrial application. Accordingly, we have synthesized a novel organic-inorganic hybrid adsorbent through in-situ growing MOF particles on electrospun polyacrylonitrile fibers (PAN) followed by modifing with amidoxime groups to form amidoximed PAN/ZIF-67 (AOPAN/ZIF) hybrid fibers. In such fibers, the N atoms from imidazole and amidoxime can improve the adsorption performance synergistically in a wide pH range, which is favorable for capturing U(VI) under nuclear wastewater and seawater. As a result, the AOPAN/ZIF fibers exhibit high adsorption amount of 498.4 mg g(-1) in U(VI) contaminated aqueous solution at pH 4. Furthermore, the adsorption amount of U(VI) reached 2.03 mg g(-1) in natural seawater after 36 d, which implies that the AOPAN/ZIF fibers may promote the development of U(VI) recovery.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据