期刊
JOURNAL OF COLLOID AND INTERFACE SCIENCE
卷 574, 期 -, 页码 174-181出版社
ACADEMIC PRESS INC ELSEVIER SCIENCE
DOI: 10.1016/j.jcis.2020.04.045
关键词
Potassium ion batteries; Anode; Amorphous carbon; SnO2 nanosheets; Hard carbon; Hollow sphere
资金
- National Natural Science Foundation of China [51704188, 51464020, 51702199, 61705125, 51875330, 51802181]
- Shaanxi University of Science and Technology [2018GBJ-04]
Potassium-ion batteries (KIBs) have becoming a prospective energy storage technique, due to the abundant potassium resources in the earth crust, approximate redox potential and similar electrochemical behavior of potassium and lithium. However, the insufficient capacity, poor stability and volume expansion of electrode materials during charge and discharge are main factors restricting the further development of KIBs. This work reports an amorphous carbon coated SnO2 nanohseets on hard carbon hollow spheres (AC/SnO2@HCHS) anode with enhanced potassium storage performance. The HCHS acts as a carrier for SnO2 nanosheets, providing high electrical conductivity and stable skeleton. The self-assembled SnO2 nanosheets with high surface area ensures sufficient contact with the electrolyte. Amorphous carbon wrapping can not only relieve SnO2 volume expansion but also provide surface-induced capacitive capacity. As a consequence, the AC/SnO2@HCHS anode presents excellent potassium-ion storage performance with high discharge capacity of 346 mAh g(-1) at 0.1 A g(-1) over 200 cycles, ultra-long cycling lifetime and outstanding rate capability (236 mAh g(-1) at 1 A g(-1) over 1000 cycles). (C) 2020 Elsevier Inc. All rights reserved.
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