期刊
JOURNAL OF COLLOID AND INTERFACE SCIENCE
卷 582, 期 -, 页码 60-69出版社
ACADEMIC PRESS INC ELSEVIER SCIENCE
DOI: 10.1016/j.jcis.2020.06.071
关键词
Melamine-based polymer networks; Hierarchically porous carbon nanobelts; Defect-rich; Fast channels; Li-ion batteries; Li-Se batteries
资金
- National Key R&D Program of China [2016YFA0202602]
- National Natural Science Foundation of China [U1663225, 21671155, 21805220]
- Sinopec Ministry of Science and Technology Basic Prospective Research Project [218025-9]
In this study, a N, O, S co-doped hierarchically porous carbon nanobelts were synthesized using organic Melamine-based porous polymer networks as a precursor, showing advanced lithium storage performance in Li-ion battery and stable cycle performance in Li-Se battery. Density function theory calculations revealed the importance of defect structures in improving the electrochemical performance.
Li-Se battery is a promising energy storage candidate owing to its high theoretical volumetric capacity and safe operating condition. In this work, for the first time, we report using the whole organic Melamine-based porous polymer networks (MPNs) as a precursor to synthesize a N, O, S co-doped hierarchically porous carbon nanobelts (HPCNBs) for both Li-ion and Li-Se battery. The N, O, S co-doping resulting in the defect-rich HPCNBs provides fast transport channels for electrolyte, electrons and ions, but also effectively relieve volume change. When used for Li-ion battery, it exhibits an advanced lithium storage performance with a capacity of 345 mAh g(-1) at 500 mA g(-1) after 150 cycles and a superior rate capacity of 281 mAh g(-1) even at 2000 mA g(-1). Further density function theory calculations reveal that the carbon atoms adjacent to the doping sites are electron-rich and more effective to anchor active species in Li-Se battery. With the hierarchically porous channels and the strong dual physical-chemical confinement for Li2Se, the Se@ HPCNBs composite delivers an ultra-stable cycle performance even at 2 C after 1000 cycles. Our work here suggests that introduce of heteroatoms and defects in graphite-like anodes is an effective way to improve the electrochemical performance. (C) 2020 Published by Elsevier Inc.
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