期刊
JOURNAL OF CHROMATOGRAPHY A
卷 1626, 期 -, 页码 -出版社
ELSEVIER
DOI: 10.1016/j.chroma.2020.461346
关键词
Molecularly imprinted polymer; Environmental water samples; Pollutants; SPE; Organophosphorus pesticides; Pesticides-oxon
资金
- Conicyt (Fondecyt Project) [1190752]
- Ministry of Science, Innovation and Universities, Spain [RTI2018-095536-BI00]
- CONICYTPFCHA/Doctorado nacional/2018 [21181488]
- Spanish Ministry of Science, Innovation and Universities
A molecularly imprinted polymer was synthesized and characterized to be used as solid-phase extraction sorbent for simultaneous chlorpyrifos and diazinon and their oxon derivatives. Several imprinted polymers were prepared and evaluated in a retention study of these analytes compared with a non-printed polymer. Several parameters affecting the extraction of imprinted polymer such as washing solvent, composition and volume of the eluting solvent and sample volume, were also investigated. Under the optimum conditions, the developed method provided satisfactory limits of detection ranging between 0.07 mu g L-1 to 0.12 mu g L-1 and the material showed an excellent reusability (> 50 reuses). The method was applied to the extraction and preconcentration of these analytes in water samples. The average recoveries ranged from 79 +/- 6 to 104 +/- 3 %. (c) 2020 Elsevier B.V. All rights reserved.
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