期刊
JOURNAL OF ALLOYS AND COMPOUNDS
卷 829, 期 -, 页码 -出版社
ELSEVIER SCIENCE SA
DOI: 10.1016/j.jallcom.2020.154562
关键词
Y2O3:Eu(3+)phosphor; Homogeneous precipitation; Monodispersed sphere
资金
- Guangxi Natural Science Foundation [2017GXNSFDA 198021, 2017GXNSFBA198075, AA138162, AA294014]
- Guangxi science and technology plan project [2018AD19079]
- High level Innovation team and Outstanding scholar Program of Guangxi Institutes
Monodispersed spherical Y2O3 powders are of great scientific interests as well as practical and technological applications. Here, the present study reports a modified homogeneous urea precipitation process to achieve monodispersed spherical Y2O3 powders using polyvinyl pyrrolidone(PVP-K30) as surface active agent. Owing to that of controlling the decomposition of urea and nucleation of metal ions with PVP-K30 as surface active agent during the precipitation process, the as-obtained precipitate precursor are monodispersed sphere with uniform particle size in a high Y3+ concentration about 0.5 M, which led to the formation uniform spherical Y2O3 particles after the calcining process at 800 degrees C for 2 h. The optical performance of spherical Y2O3:Eu3+ was also studied, which displayed strong red emission peak at 613 nm ascribed to D-5(0)-> F-7(2) forced electric dipole transition of Eu3+. All these critical characteristics suggest that the as-obtained Y2O3 powders hold promising applications in bioimaging, solid-state lighting, display devices and functional ceramics. (C) 2020 Elsevier B.V. All rights reserved.
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