期刊
INTERNATIONAL JOURNAL OF HYDROGEN ENERGY
卷 45, 期 50, 页码 26490-26500出版社
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.ijhydene.2020.05.070
关键词
PEMFC stack; Dynamic loading strategies; Single-cell voltage uniformity
资金
- National Key R&D Program of China [2017YFB0102802]
The operating life of the proton exchange membrane fuel cell stack is mainly decided by performances of its weakest single cell because of the Buckets effect, thus high voltage uniformity during a dynamic loading process is key to the stack durability. In this work, a 3-kW stack is examined experimentally on its voltage uniformity (voltage coefficient variation (Cv)) under conditions of loading from open-circuit state (0 A) to nominal current (165 A) and stack temperatures of 30 degrees C, 45 degrees C and 65 degrees C. Different dynamic loading stra- tegies, namely constant loading rate strategy, decreasing loading rate strategy, and increasing loading rate (square/cube increasing loading rate) strategy, are examined and compared. Results display that during the loading process, (a) the voltage uniformity rises abruptly and goes down quickly when the loading current is small (e.g. from 0 A to 22 A), (b) the voltage uniformity under a small loading current is better than that under the opencircuit state, and (c) voltage uniformity decreases as the loading current increases from a small value to the nominal current. Comparisons of different current loading strategies show that as the stack temperature rises from 30 degrees C to 65 degrees C, the stack Cv value under the open-circuit state increases from 1.12 to 1.84 and decreases from 3.85 to 2.45 in the nominal current state. The maximum Cv for the decreasing loading rate strategy decreases from 16.25 to 9.49 and that of the constant loading rate strategy also decreases from 5.85 to 4.96. Cv values of the square current increasing loading rate strategy keep below 3.85 under conditions of the three stack temperatures and display a slight fluctuation during the whole current loading process, which indicates that the strategy can effectively make the stack being of an excellent voltage uniformity during the instantaneous response process. (C) 2020 Hydrogen Energy Publications LLC. Published by Elsevier Ltd. All rights reserved.
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