期刊
INTERNATIONAL JOURNAL OF HYDROGEN ENERGY
卷 45, 期 51, 页码 26989-26999出版社
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.ijhydene.2020.07.006
关键词
Defects; Polyaniline; Layered double hydroxides; Hydrogen evolution reaction; Oxygen reduction reaction
资金
- Natural Science Foundation of China [21603017]
- China Postdoctoral Science Foundation [2016M601355]
- Natural Science Foundation of Jilin Province, China [20170101095JC]
- International Cooperation Project of Jilin Province [20190701022GH]
- Innovative Foundation of Changchun University of Science and Technology [XJJLG-2016-01]
Here, Fe, Co-layereddoublehydroxide andpolyaniline compositesontonickel foam(NF) (FeCo-LDH/PANI) were fabricated via one-step co-electrodepositionmethod. The test results indicate the co-existence of the amorphous structure and the smaller size of crystal districtwith more defects inoptimal FeCo-LDH/PANI. Importantly, it is found that there aremore defects in FeCo-LDH/PANI compared to that of FeCo-LDHpossibly attributed to the local etching of H+ released from the polymerization of aniline. Benefitting from the numerous defects, higher electrochemical surface area (ECSA), lower charge-transfer resistance and electron interaction, the optimized FeCo-LDH/PANI needs the overpotentials of 104, 246, 285 and 323 mV vs RHE for hydrogen evolution reaction (HER) and oxygen evolution reaction (OER) to achieve 10 and 100mAcm(-2), and shows desirable stability. Noticeably, the optimal FeCo-LDH/PANI requires a cell voltage of 1.53 V to drive 10 mA cm(-2) for the whole water splitting. (C) 2020 Hydrogen Energy Publications LLC. Published by Elsevier Ltd. All rights reserved.
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