期刊
INTERNATIONAL JOURNAL OF HYDROGEN ENERGY
卷 45, 期 32, 页码 16049-16059出版社
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.ijhydene.2020.04.005
关键词
Bacterial cellulose; Carbon aerogel; Nickel sulfide; Methanol oxidation
资金
- National Natural Science Foundation of China [51101140]
- Natural Science Foundation of Zhejiang Province of China [LY16E010004]
In this study, carbon aerogel (CA) were obtained by inexpensive bacterial cellulose (BC) hydrogel freeze-dried and carbonized under N-2 atmosphere. Then nickel sulfide (NiS)/CA composite aerogel electrodes with different contents were successfully prepared by a one-step solvothermal method. The morphology, phases and surface electronic state of these electrodes were characterized by SEM/TEM, XRD and XPS, respectively, and their electro-catalytical properties for methanol oxidation were investigated by cyclic voltammetry (CV) in the alkaline media of methanol. The NiS particles dispersed uniformly on CA, and the obtained material maintained the reticulated porous structure of BC. The methanol oxidation peak current density of CNS-0.5 at 0.8 V reached 43 mA/cm(2) (263 mA/mg). After 1000 cycles, the peak current density retained 92% of the initial state. The composite electrode has good catalytic activity and good cycle performance for methanol catalysis. Nickel sulfide with high crystallinity transforms to nickel oxide with low crystallinity after a long cycle test, which results in excellent cycle performance of the composite. NiS/CA electrodes have the potential for application in portable or wearable devices. (C) 2020 Hydrogen Energy Publications LLC. Published by Elsevier Ltd. All rights reserved.
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