期刊
FOOD CHEMISTRY
卷 314, 期 -, 页码 -出版社
ELSEVIER SCI LTD
DOI: 10.1016/j.foodchem.2020.126214
关键词
Ferrofluid; Supramolecular solvents; Polycyclic aromatic hydrocarbons; Gas chromatography-flame ionization detector; Box-Behnken design
资金
- Fundamental Research Grant Scheme, Ministry of Higher Education (MOHE), Malaysia (FRGS) [FP071-2018A]
- University Malaya Faculty Research Grant [GPF058B-2018]
- Malaysian Pharmaceutical Industries (MPI) Sdn. Bhd
Poly(beta-cyclodextrin-ionic liquid) grafted magnetic nanoparticles combined with 1-octanol as supramolecular solvents (SUPRASs) presenting new ferrofluid was developed and successfully applied in the dispersive liquid-phase microextraction of seven representative polycyclic aromatic hydrocarbons. One variable at-a-time (OVAT) analysis and response surface methodology (RSM) were used for efficient optimization of the main variables. The calibration curves were found to be linear in the range of 0.1-150 ng mL(-1) with correlation of determinations (R-2) ranging from 0.9944 to 0.9986. Detection limits ranged at 0.02-0.07 ng mL(-1) for all studied PAHs. The intra and inter-day precision values (RSD %) were in the range of 1.80%-7.56% and 2.97%-8.23%, respectively. The ferrofluid showed a satisfactory reproducibility between 1.72% and 5.90%, and acceptable recovery values at 84%-110% were obtained for the real samples analysis. The optimized method was successfully applied to access the content safety of the PAHs studied in a variety of commercial food and beverages available in Malaysia.
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