Investigation on the conditions leading to the micro-explosion of emulsified fuel droplet using two colors LIF method

Biofuels in the form of water-in-oil (W/O) emulsions are a promising substitution for hydrocarbon fuels, mainly thanks to the micro-explosion phenomenon that occurs under strong heating. Micro-explosion is the atomization of a W/O emulsion drop into daughter droplets because of the water embedded droplets phase change. This atomization leads to the reduction of pollutants and unburnt hydrocarbons emissions. However, micro-explosion is not a systematic phenomenon: indeed, for some cases the water phase change is weak and leads to a partial atomization, called Puffing. This paper relates a novel approach to better understand the occurrence of micro-explosion. It consists on the identification of the drop triggering the atomization, called the trigger drop, and measure its properties (temperature, size and position within the emulsion drop) thanks to non-intrusive optical diagnostics. Two colors laser induced fluorescence (LIF2C) is the main method used in this work for temperatures. These temperature measurements showed promising results of both quantitative and qualitative aspects. After the calibration steps and the method validation, it is applied for the temperature measurements of water droplets embedded in oil with the maximum temperature recorded around 130 degrees C. Using these measurements methods, a correlation is found between quality of atomization (either micro-explosion or puffing) and the properties of the trigger drop (temperature, size and position). When one of these parameters is not optimal, it can indeed be compensated by the others.