期刊
EUROPEAN JOURNAL OF ORGANIC CHEMISTRY
卷 2020, 期 34, 页码 5473-5487出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/ejoc.202000660
关键词
Reaction mechanisms; Noncovalent interactions; Organocatalysis; Synthesis; Calculations
资金
- Fonds der Chemischen Industrie
- Deutschen Forschungsgemeinschaft [BR 5154/2-1]
Noncovalent interactions like halogen, chalcogen, and pnictogen bonding are known for a very long time. During the last decade, these interactions have found different applications in catalysis. These forces are often called sigma-hole interactions which can be explained by the anisotropic distribution of the electron density around these atoms. In this MiniReview, we will present recent applications of halogen, chalcogen, and pnictogen bonding in catalysis and discuss experimental and computational investigations to gain more insights into the underlying mechanisms.
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