期刊
EUROPEAN JOURNAL OF ORGANIC CHEMISTRY
卷 2020, 期 33, 页码 5388-5393出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/ejoc.202000822
关键词
Asymmetric synthesis; Chiral ligands; Cycloaddition; Synthetic methods; Zinc
资金
- Polish National Science Centre [2016/21/N/ST5/00885]
Asymmetric hetero-Diels-Alder reactions of Danishefsky's diene and glyoxylate/pyruvate esters catalyzed by readily available zinc triflate complex with BOX ligand afforded the corresponding adduct which upon treatment with trifluoroacetic acid furnished the hetero-Diels-Alder product in 91 % enantiomeric excess and 87 % isolated yield. This reaction was applied to the concise synthesis of six-membered ulosonic acidC-glycoside.
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