Lanthanum hydroxide: a highly efficient and selective adsorbent for arsenate removal from aqueous solution

In the present work, a lanthanum hydroxide adsorbent was prepared by a simple precipitation process, and its arsenic removal performances and adsorption mechanisms were investigated by batch experiments and various techniques including field emission scanning electron microscopy with energy-dispersive X-ray spectrophotometry (FESEM-EDX), Brunauer-Emmett-Teller (BET) analysis, powder X-ray diffraction (p-XRD), Fourier transform infrared spectroscopy (FTIR), and X-ray photoelectron spectroscopy (XPS). The influence of pH on arsenic removal showed that the lanthanum hydroxide adsorbent can effectively remove As(V) from solution, whereas the As(III) removal was very low, indicating that the lanthanum hydroxide adsorbent can selectively remove As(V) but not As(III). The isotherm study showed that the maximum adsorption capacities of As(V) at pH 5.0 and 9.0 were 299.4 and 192.3 mg/g, respectively, much higher than those of the widely used ferrihydrite. Significant interference on As(V) removal was caused by the presence of phosphate and natural organic acids (NOAs), such as citric acid. Powder XRD, FTIR, and XPS analysis showed that the lanthanum hydroxide was almost transformed into lanthanum arsenate after As(V) adsorption at pH 4.0, while a portion of lanthanum hydroxide remained after As(V) adsorption at pH 6.0 and 9.0. Furthermore, ligand exchange between the hydroxyl groups of the adsorbent and As(V) and the formation of inner-sphere surface complexes could play a central role in arsenic removal which needs further investigation.