期刊
ENVIRONMENTAL RESEARCH
卷 185, 期 -, 页码 -出版社
ACADEMIC PRESS INC ELSEVIER SCIENCE
DOI: 10.1016/j.envres.2020.109467
关键词
U(VI); Fe3O4/AC; Adsorption mechanism; XPS; Modeling
资金
- National Natural Science Foundation of China [21822602]
- Jiangsu Provincial Key Laboratory of Radiation Medicine and Protection
- Priority Academic Program Development of Jiangsu Higher Education Institutions
A robust prediction of U(VI) on Fe3O4/activated carbon (Fe3O4/AC, fabricated by co-precipitation method under N-2 conditions) under different pH was developed via diffuse layer model, in accordance with FI-IR, XRD and XPS analysis. No influence of ionic strength onto U(VI) adsorption by Fe3O4/AC under ambient conditions suggested the inner-sphere surface adsorption, which was attributed to abundant surficial functional groups according to FT-IR and XPS analysis. The batch experiments indicated Fe3O4/AC with fast adsorption rate (equilibrium within 60 min), high adsorption capacity (56 mg/g at pH 4.0) towards U(VI). The adsorbed U(VI) was partly reduced by Fe2+ of Fe3O4/AC by XPS analysis. Surface complexation modeling showed that a single set of monodentate and mononuclear species (SOUO2+) cannot predict U(VI) adsorption at high pH, whereas the robust prediction of U (VI) adsorption over wide pH range was observed by adding the other binuclear and tridentate species ((SO)(2)UO2(CO3)(6-)). These findings revealed that magnetic AC as a candidate for immobilization and/or pre-concentration of radioactive wastewater in environment management.
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