期刊
ENERGY & FUELS
卷 34, 期 8, 页码 10067-10077出版社
AMER CHEMICAL SOC
DOI: 10.1021/acs.energyfuels.0c01703
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资金
- Ministry of Education (MOE) - Brain Korea 21 Plus [21A20132000001]
- National Research Foundation of Korea [21A20132000001] Funding Source: Korea Institute of Science & Technology Information (KISTI), National Science & Technology Information Service (NTIS)
The membrane electrode assembly (MEA) is considered as the center of the polymer electrolyte membrane fuel cell (PEMFC); a solid electrolyte membrane is an indispensable component of MEA. For membrane research and development, reducing ohmic resistance while improving mechanical stability is a challenge. Using short-side-chain (SSC) Aquivion perfluorosulfonic acid (PFSA) dispersion and considering the theory of coordination networks, the conductivity of the Aquivion polymer electrolyte membrane is improved by incorporating a highly proton-conductive and economical three-dimensional MOF {[(Me2NH2)(3)(SO4)](2)[Zn-2(ox)(3)]}(n). The proton conductivity of the 1 wt % MOF-1/Aquivion composite membrane was improved by 13% compared to that of the pristine Aquivion membrane, 2 times that of Nafion and 1.5 times that of the MOF-1/Nafion composite. The water uptake and the ion-exchange capacity values are measured to analyze the fundamental properties of the membranes, and physical characterization techniques are also used.
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