期刊
ENERGY & FUELS
卷 34, 期 7, 页码 8432-8439出版社
AMER CHEMICAL SOC
DOI: 10.1021/acs.energyfuels.0c01128
关键词
-
资金
- National Natural Science Foundation of China [21965018, 21706223]
Catalytic transfer hydrogenation (CTH) of 5-hydroxymethylfurfural (HMF) into 2,5-bis(hydroxymethypfuran (BHMF) is an important method for the catalytic upgrading of biomass-derived platform compounds to fuels and chemicals, and the development of effective and economical catalysts for this purpose is of great significance. In this work, we designed and prepared a new carbon-nanosheets (CNS)-supported Zr/Ca bimetallic catalyst (ZrCa@CNS) with low cost by a gel-blowing strategy. Comprehensive studies revealed that ZrCa(2)@CNS-600 exhibited good catalytic activity on the CTH of HMF into BHMF via Meerwein-Ponndorf-Verley (MPV) reduction, and an 84.2% BHMF yield with a 91.2% HMF conversion was obtained in isopropyl alcohol at 190 degrees C in 10 h. ZrCa(2)@CNS-600 exhibited good heterogeneity, reusability, and stability, and it is readily recovered from the reaction mixture by filtration and consecutively recycled/reused for six times without an obvious loss in its catalytic activity.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据