期刊
DYES AND PIGMENTS
卷 178, 期 -, 页码 -出版社
ELSEVIER SCI LTD
DOI: 10.1016/j.dyepig.2020.108347
关键词
Fluorescence detection; Tertiary butylhydroquinone (TBHQ); Edible oils; Samarium organic metal framework; Energy transfer
资金
- National Natural Science Foundation of China [U1604143, U1804131]
- Training Program for Young Cadre Teachers of Higher Education Institutions in Henan Province [2018GGJS128]
- Science and Technology Development Project in Henan Province [172101410037]
A turn off-on samarium-metal-organic-framework (Sm-MOF) fluorescence sensor for detection of tertiary butylhydroquinone (TBHQ) in edible oil was designed. It was found that the fluorescence of Sm-MOF was quenched in the presence of Fe3+ ion by forming Sm-MOF@Fe3+ complex (turn off), then it was recovered after adding TBHQ (turn on) due to the competitive formation of TBHQ@Fe3+ and release of Sm-MOF. Under the optimum Fe3+ concentration, the fluorescence turn off-on approach exhibited superior selectivity and sensitivity, wide linear range (0-120 mu g/mL) and low detection limit (5.6 ng/mL) toward TBHQ. The fluorescence recovery selectivity of TBHQ over other synthetic phenolic antioxidants was attributed to the synergistic effect of high EHomo value and a small space steric hindrance. TBHQ spiked in edible oil was quantitatively detected by the standard curve method with recoveries of 101.2%-103.0%, suggesting that the turn off-on approach has potential application for TBHQ detection in oil-containing foods.
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