期刊
CURRENT ORGANIC CHEMISTRY
卷 24, 期 22, 页码 2588-2600出版社
BENTHAM SCIENCE PUBL LTD
DOI: 10.2174/1385272824999200622115655
关键词
Palladium; heterogeneous and homogeneous catalysis; coupling reaction; CO surrogates; carbonylation; CO gas free; green synthesis
Carbonylation reactions with carbon monoxide (CO) provide efficient and attractive routes for the synthesis of bulk and fine chemicals. However, the practice of using a large excess of an inflammable, lethal and greenhouse CO gas is always a concern in this chemistry. The development of CO surrogates has gained substantial interest and become a green alternative to gaseous CO. Many of the recent studies have focused on the development of other benign and safe reagents to work as a CO source in carbonylation reactions, and the assortment of feasible CO surrogates for specific reaction can be accomplished by the literature data. This review describes the recent developments in palladium-catalyzed carbonyl insertions without the direct use of gaseous CO.
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