期刊
CRYSTAL GROWTH & DESIGN
卷 20, 期 10, 页码 6421-6429出版社
AMER CHEMICAL SOC
DOI: 10.1021/acs.cgd.0c00581
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资金
- National Chi Nan University
- Ministry of Science and Technology, Taiwan [105-2119-M-260-006-MY3, 108-2113-M-260-008-]
Reaction of tert-butyl 3,5-diaminobenzoate with cyanuric chloride gave triazine-based macrocycle 1 in 44.3% yield, which was characterized by H-1 and C-13 NMR spectroscopy, mass spectrometry, and elemental analysis. A thermally stable HOF-1 from macrocycle 1 was crystallized from hexane-THF, and its porous property was studied. The crystallographic analysis revealed that the void space was maintained by the pi-pi, H-bond, and C-H-pi interactions between the aromatic moieties in a solid state. The framework changes while losing solvents and produces various emission intensities when irradiated. After completely removing the solvents, the void space of HOF 1 was still available for solvation, and surprisingly, the framework almost recovered after adsorbing solvents according to the powder-XRD study.
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