期刊
CHINESE JOURNAL OF CHEMISTRY
卷 38, 期 11, 页码 1395-1421出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/cjoc.202000160
关键词
Chiral phosphine; Organocatalysis; Asymmetric reaction; Cycloaddition; Domino reaction; (aza)-MBH reaction
资金
- Strategic Priority Research Program of the Chinese Academy of Sciences [XDB20000000]
- National Natural Science Foundation of China [21572052, 21421091, 21772226, 21772037, 21861132014]
Chiral tertiary phosphines are versatile Lewis base catalysts capable of promoting a wide range of asymmetric reactions. In particular, the recent designed chiral phosphines based on the concept of bi-/multifunctionality have been demonstrated to be effective catalysts for many types of asymmetric reactions such as (aza)-MBH reaction/RC reaction, cycloaddition reaction, domino reaction, nucleophilic addition reaction,etc. This review summarizes the recent advances in this field and highlights the selected significant achievements.
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