期刊
CHEMSUSCHEM
卷 13, 期 18, 页码 4776-4794出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/cssc.202001165
关键词
alkynes; C-H activation; cross-dehydrogenative coupling; homogeneous catalysis; hydrocarbons
资金
- NSFC [HSFHN 2019MS005]
- Fundamental Research Funds for the Central Universities (Hainan University) [21871070]
Alkynes are among the most fundamentally important organic compounds and are widely used in synthetic chemistry, biochemistry, and materials science. Thus, the development of an efficient and sustainable method for the preparation of alkynes has been a central concern in organic synthesis. Cross-dehydrogenative coupling utilizing E-H and Z-H bonds in two different molecules can avoid the need for prefunctionalization of starting materials and has become one of the most straightforward methods for the construction of E-Z chemical bonds. This Review summarizes recent progress in the preparation of internal alkynes by cross-dehydrogenative coupling with terminal alkynes.
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