期刊
CHEMOSPHERE
卷 263, 期 -, 页码 -出版社
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.chemosphere.2020.127947
关键词
Microplastics; Soil; Triclosan; Adsorption; Desorption
资金
- National Natural Science Foundation of China [41907116]
- Natural Science Foundation of Jiangsu Province [BK20191040]
- Jiangsu Overseas Visiting Scholar Program for University Prominent Young & Middle-aged Teachers and Presidents
The study found that polyethylene (PE) had the highest adsorption rate and equilibrium capacity for triclosan (TCS), while soil and polystyrene (PS) were similar. The addition of PE increased TCS sorption in soil, while PS had no significant influence.
Microplastic (MP) pollution in soil has been becoming an emerging environmental hot spot, but little is known about the interaction between MPs and chemical contaminants in soil. In this study, batch experiments were performed to study adsorption-desorption behavior and mechanism of triclosan (TCS) on MPs, polyethylene (PE) and polystyrene (PS), and soil particles. PE showed the highest adsorption rate (29.3 mg mg(-1) h(-1)) and equilibrium capacity (1248 mg g(-1)), while the similar profiles between PS (0.27 mg mg(-1) h(-1) and 1033 mg g(-1), respectively) and soil (0.60 mg mg(-1) h(-1) and 961 mg g(-1), respectively). Two adsorption stages, representing liquid-film and intra-particle diffusion were observed obviously for PE. Adsorption isotherm results revealed that the interaction between MPs and TCS was relatively weak. The sorption potential of soil was lower than that of MPs especially at high concentrations. PE addition induced TCS sorption increase in soil, while PS had no significant (P > 0.05) influence. For MP-soil systems, TCS preferred to adsorb on MPs, which was more pronounced for PE than PS. The desorption rate of TCS was the highest for soil, followed by PE and PS, while equilibrium release amount ranked: PE > PS > soil. Moreover, soil solution better facilitated the desorption, with the amount increasing by 38% for PE compared with 0.01 M CaCl2 solution. Therefore, MPs, especially PE with high adsorption and desorption potentials may serve as a source and carrier to TCS, and its amendment can change TCS environmental behavior and further risk in soil. (C) 2020 Elsevier Ltd. All rights reserved.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据