期刊
CHEMISTRY-A EUROPEAN JOURNAL
卷 26, 期 66, 页码 15290-15297出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/chem.202003622
关键词
alkylation; C-H activation; heterogeneous catalysis; meta-selectivity; photocatalysis
资金
- European Union's Horizon 2020 Framework Program H2020/2014-2020/ [NMBP-01-2016, 720996]
- DFG [SPP1807]
- Kwanjeong Educational Foundation
- Projekt DEAL
We disclose the unprecedented hybrid-ruthenium catalysis for distalmeta-C-H activation. The hybrid-ruthenium catalyst was recyclable, as was proven by various heterogeneity tests, and fully characterized with various microscopic and spectroscopic techniques, highlighting the physical and chemical stability. Thereby, the hybrid-ruthenium catalysis proved broadly applicable formeta-C-H alkylations of among others purine-based nucleosides and natural product conjugates. Additionally, its versatility was further reflected bymeta-C-H activations through visible-light irradiation, as well aspara-selective C-H activations.
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