期刊
CHEMISTRY-A EUROPEAN JOURNAL
卷 26, 期 44, 页码 9749-9783出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/chem.202001832
关键词
cascade reaction; C-H activation; heterocycle synthesis; transition metal
资金
- Board of Research in Nuclear Sciences Funding Source: Medline
Sequential, domino and tandem reactions could be defined as a sequence of synthetic transformations that occur one after the other, in the same reaction flask. This Review highlights recent advances at the overlap of two worlds: transition-metal mediated C-H activation as a trigger of cascade reaction, for the heterocycles synthesis. To shed some light on this intricate middle-earth, focus was put on the reaction mechanism rather than the type of metal or the chronological order of the reaction. The aim is to separate, and then highlight, the true domino reactions initiated by C-H activation, compared to other examples of C-H functionalization for heterocycle syntheses.
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