期刊
CHEMISTRY-A EUROPEAN JOURNAL
卷 26, 期 64, 页码 14530-14535出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/chem.202002664
关键词
azasydnone; energetic materials; explosive; heterocycles; high nitrogen compounds
资金
- Army Research Office (ARO) [W911NF-18-1-0463]
- Purdue University
- Office of Naval Research (ONR)
- National Science Foundation [CHE 1625543]
- Department of Chemistry and Life Science, United States Military Academy
This work reports the first compound containing both a tetrazole and an azasydnone ring, a unique energetic material. Several energetic salts of the tetrazole azasydnone were synthesized and characterized, leading to the creation of new secondary and primary explosives. Molecular structures are confirmed by(1)H and(13)C NMR, IR spectroscopy, and X-ray crystallographic analysis. The high heats of formation, fast detonation velocities, and straight-forward synthesis of energetic azasydnones should capture the attention of future energetics research.
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