期刊
CHEMICAL REVIEWS
卷 120, 期 16, 页码 8987-9014出版社
AMER CHEMICAL SOC
DOI: 10.1021/acs.chemrev.9b00803
关键词
-
资金
- U.S. Department of Energy's Office of Energy Efficiency and Renewable Energy under the Hydrogen and Fuel Cell Technologies and Vehicle Technologies Offices [DE-EE0008813]
As compared to porous network solids, including metal-organic frameworks, covalent-organic frameworks, porous aromatic frameworks, and zeolites, porous molecular materials are relatively unexplored. Additionally, within porous molecular space, porous organic cages (POCs) have been the most widely reported over the past decade. Relatively recently, however, porous hybrid metal-organic molecular complexes have received considerable attention with a large fraction of surface areas for these coordination cages reported over the past three years. This review focuses on advances in this area. We highlight the recent work with permanently microporous metal-organic polyhedra (MOPs). Analogous to early work in the area of MOFs, the vast majority of MOPs for which surface areas have been reported have been based on paddlewheel building units and carboxylate ligands. We describe the synthesis of porous cages and highlight those based on monometallic, bimetallic, trimetallic, tetrametallic, and higher nuclearity clusters. Finally, we showcase work wherein the porosity of MOPs has been leveraged for applications related to the storage and separation of small molecules and the incorporation of these porous and potentially porous cages into membranes.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据