期刊
CHEMICAL RESEARCH IN CHINESE UNIVERSITIES
卷 36, 期 4, 页码 560-583出版社
HIGHER EDUCATION PRESS
DOI: 10.1007/s40242-020-0187-y
关键词
Two dimensional(2D) nanomaterial; Batteries beyond Li ion; In situtechnique; Atomic-level; Storage mechanism and kinetics
资金
- Fundamental Research Funds for the Central Universities of China [2018JBZ107]
- Key Program for International SAMP
- T Cooperation Projects of China [2018YFE0124600]
- National Natural Science Foundation of China [91961125, 21903001]
- Funds of the Chemistry and Chemical Engineering Guangdong Laboratory, China [1932004]
Developing new types of rechargeable batteries with high energy densities and low cost have received increasing attentions, aiming to reduce the dependence on high-priced lithium. Beyond Li-ion batteries, the potential alternatives including Na-ion batteries, Li-S batteries and Li-air batteries have been investigated recently, which are required to be viable for commercial applications. From this point of view, to understand the electrochemical reaction mechanisms and kinetics of these batteries has become the key challenge to make breakthroughs in the field of new energy storage. In this review, we present a critical overview of the two dimensional nanomaterials-based batteries (except Li-ion-based batteries) that could meet such demonds. To develop new energy storage devices with more promising performances, the microstructure evolution and atomic scale storage mechanism of these batteries are comprehensively summarized. In addition, the major challenges and opportunities of advanced characterization techniques are finally discussed. We do hope that this review will give the readers a clear and profound understanding of the electrochemical reaction mechanisms and kinetics of the as-discussed batteries, thus effectively contributing to the smart design of future-generation energy storage devices.
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