期刊
CERAMICS INTERNATIONAL
卷 46, 期 10, 页码 16257-16265出版社
ELSEVIER SCI LTD
DOI: 10.1016/j.ceramint.2020.03.182
关键词
Carbides; Borides; Solid solution; Grain boundary; Fracture toughness
资金
- National Natural Science Foundation of China [U19A2099, 51902197]
- Shanghai Pujiang Program [18PJ1406500]
HfC-HfB2 composite ceramics were successfully reactively spark plasma sintered with a unique SiB6 additive. The incorporation of the SiB6 not only promotes the densification of HfC (up to similar to 99%), but also significantly enhances the toughness from 4.3 +/- 0.5 MPa m(1/2) to 14.2 +/- 1.4 MPa m(1/2). The flexural strength of the HfC-HfB2 composite ceramics was simultaneously improved to 529 +/- 48 MPa, which is about 1.4 times higher than that of HfC. This improvement is attributed to the dense composite microstructure comprising an in-situ formed HfB2 and a solid solution of Si and O in HfC and HfB2 grains.
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