期刊
CERAMICS INTERNATIONAL
卷 46, 期 10, 页码 15379-15384出版社
ELSEVIER SCI LTD
DOI: 10.1016/j.ceramint.2020.03.082
关键词
Porosity engineering; Graphene; Covalent-linkage; Energy storage
资金
- National Key Research and Development Program of China [2017YFA0206700, 2017YFA0402802]
- National Natural Science Foundation of China [21776265, 51902304]
- Natural Science Foundation of Anhui Province [1908085ME122]
- Fundamental Research Funds for the Central Universities [Wk2060140026]
Graphene is a promising material in supercapacitors. However, the restacking of graphene sheets during electrode fabrication or under service conditions greatly reduces the capacity for energy storage. Rationally designing a stable and robust 3-D framework of a graphene-based electrode is important for high-performance energy storage devices. Here we demonstrated a novel strategy to engineer the micropore structure in reduced graphene oxide materials for supercapacitors. Anthraquinone molecules as covalently-linked pillars were used to construct graphene framework and prevented the restacking of graphene sheets during fabrication processes. Compared with traditional reduced graphene oxide, the covalently-linked graphene framework contained numerous micropores, and therefore significantly enhanced the performance in supercapacitors. Moreover, this anthraquinone-functionalized graphene framework could also achieve a higher specific capacity in lithium batteries due to the additional Faradaic reaction in oxygen functional groups.
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