期刊
CARBON
卷 164, 期 -, 页码 198-206出版社
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.carbon.2020.03.054
关键词
Nickel; Oxygen; Graphene; Scanning tunneling microscopy
资金
- Russian Foundation for Basic Research (RFBR) [16-29-06426]
This paper reports an STM study of all stages of the intercalation of oxygen at the interface of a strongly coupled graphene/Ni(111) system prepared by temperature programmed growth (TPG) method. We have found that at the first stage of the intercalation at 120 degrees C, oxygen forms a chemisorbed layer on Ni(111) with a coverage about 0.26-0.28 ML, approximately described by the compressed p(2 x 2) lattice. The second stage of the intercalation is the formation of a single NiO(100) layer visualized in STM images as a specific 'square' superstructure at the graphene/Ni(111) interface. It was also established that the rate of the oxygen intercalation at 250 degrees C is much higher than at 120 degrees C. After intercalation at 250 degrees C, STM also reveals the formation of regions with 'free-standing' graphene, associated with the presence of a double nickel oxide layer underneath. (C) 2020 Elsevier Ltd. All rights reserved.
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