期刊
CARBOHYDRATE POLYMERS
卷 242, 期 -, 页码 -出版社
ELSEVIER SCI LTD
DOI: 10.1016/j.carbpol.2020.116402
关键词
Magnetite, carboxymethyl cellulose; Porous carbon; Hydrogel; Metal and dye adsorption
资金
- Academy of Scientific Research and Technology (ASRT), Egypt and Czech Academy of Sciences [ASRT-19-06]
- Czech Science Foundation [19-06065S]
Adsorption is the most efficient technique for the removal of metal ions and organic dyes from water. This stimulates demand for the preparation of eco-friendly adsorbents. In this study, magnetic hydrogels based on a crosslinked carboxymethyl cellulose grafted acrylamide (CMC-g-AM) embedded with porous carbon (PC) and citric acid-modified magnetite were prepared. PC was synthesized via single-step oxidation of bagasse under muffled atmosphere condition. The magnetite (Fe3O4) nanoparticles were synthesized using the co-precipitation method (Fe2+/Fe3+) and citric acid modification (CFe). Functionality and parameters of adsorbent were characterized by infrared spectroscopy, scanning electron microscopy, and energy-dispersive X-ray. The magnetic hydrogels have a highly effective performance for Pb-ions and methylene blue dye (MB) removal from water due to the unique role of crosslinked CMC matrix in supporting synergy between embedded PC and CFe. Adsorption testing using time intervals (5-120 min) and Pb-ions and MB concentrations (5-500 mg/L) indicate that CMC-g-AM containing equal content of PC and CFe has substantially higher removal efficiency; 70.8 and 96.1 % against 47.8 and 30.2 % (without PC and CFe) for Pb-ions and MB adsorption respectively for CMC-g-AM. The equilibrium time and the maximum sorption capacity (qm) from the adsorption studies were found to be 60 and 30 min and 294.1 and 222.2 mg/g for Pb-ions and MB respectively. The kinetics and isotherms were studied to highlight the adsorption rate and mechanism of the adsorption process.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据