期刊
BIORESOURCE TECHNOLOGY
卷 309, 期 -, 页码 -出版社
ELSEVIER SCI LTD
DOI: 10.1016/j.biortech.2020.123383
关键词
Industrial hemp; Biomass pretreatment; Enzymatic hydrolysis; Bioethanol production; Morphological characterization
In this work, four varieties of hemp biomasses (Helena, SS Beta, Tygra, and Elleta Campana) pretreated with liquid hot water (LHW), H2SO4, and NaOH were investigated for ethanol production. Physicochemical and morphological properties of the pretreated hemp biomass were characterized. LHW achieved high glucan (85-98%) and xylan (67-71%) recoveries. H2SO4 induced significant glucan decomposition (5.9-10.6 g/L) and inhibitor formation (4.5-7.4 g/L of HMF and 2.8-4.5 g/L of furfural) in resulting slurries. Both LHW and H2SO4 pretreatments resulted in low glucose and ethanol yields due to recondensed lignin units. NaOH pretreatment achieved high glucose and ethanol yields due to efficient lignin removal (58.6-75.3%). There was no significant variation in ethanol yield among the four hemp varieties pretreated by NaOH. H2SO4 and NaOH pretreated biomasses showed apparent terraced-field structures and microporous protuberances. Changes in crystallinity indexes and intensities of FTIR peaks were consistent with enhanced cellulose and decreased amorphous hemicellulose.
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